Aqueous Photo-Living Radical Polymerization of Sodium Methacrylate Using a Water-Soluble Nitroxide Mediator
نویسندگان
چکیده
منابع مشابه
Synthesis of Stimuli-responsive, Water-soluble Poly[2-(dimethylamino)ethyl methacrylate/styrene] Statistical Copolymers by Nitroxide Mediated Polymerization
2-(Dimethylamino)ethyl methacrylate/styrene statistical copolymers (poly(DMAEMA-stat-styrene)) with feed compositions fDMAEMA = 80–95 mol%, (number average molecular weights Mn = 9.5–11.2 kg mol) were synthesized using succinimidyl ester-functionalized BlocBuilder alkoxyamine initiator at 80 °C in bulk. Polymerization rate increased three-fold on increasing fDMAEMA = 80 to 95 mol%. Linear Mn in...
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Free radical polymerization is one of the most widely employed polymerization techniques. This technique is applied to prepare latexes to be used in paints, high molecular weight poly (methyl methacrylate) for safety glass (Plexiglas), or foamed poly (styrene) to be applied in coffee cups. Some advantages of radical polymerizations, with respect to other techniques, are the relative insensitivi...
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ژورنال
عنوان ژورنال: ISRN Polymer Science
سال: 2012
ISSN: 2090-8733
DOI: 10.5402/2012/630478